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The advantages of an acausal modeling approach, when scaling-up individual cell models into a complete battery system are also presented.
The model structure adopted for the battery cell is based on an equivalent circuit representation.
The circuit elements are modified to take account of both hysteresis and diffusion limitation.
However, due to their complexity and computational burden, they are arguably of less value for system level analysis and the management of automotive energy storage systems.
In recent years, several simplifications to these models have been published in an attempt to improve their run-time performance associated with resolving solid phase diffusion .
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Using statistical analysis of battery tests, cell model parameter variations are characterized and quantified.
The cell and scaled-up pack model are parameterized for a number of commercially available cell formats, energy capacities and chemistries.
Extensions to porous electrode theory have focused on improving our understanding of the dynamics of non-ideal active materials [8,9,10,11], charge transfer kinetics [10,12] and the structural characterization of electrode microstructures .
The development of high fidelity single cell models is of immense value to the scientific community investigating novel cell designs and innovations in material science.